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Alpha-olefin hydrolysis typically refers to the conversion of alpha-olefin sulfonates (AOS) or intermediates into surfactants, involving the base hydrolysis of sultones (cyclic sulfate esters) and sulfonic acids. This process converts sulfonation products into a mixture of alkenesulfonates and hydroxyalkanesulfonates (60-65% and 35-40% respectively).
Key Aspects of Alpha-Olefin Sulfonate Hydrolysis:
- Process Overview: Alpha-olefins are sulfonated with , producing allylic/homoallylic sulfonic acids and 5- or 6-membered cyclic sulfate esters (sultones).
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Web results
Unit 11 Alpha Olefins Hydrolysis
WEIXIAN (Nanjing) Science Technology co., ltd
https://www.njweixian.com › unit-11-alpha-olefins-hydr...
WEIXIAN (Nanjing) Science Technology co., ltd
https://www.njweixian.com › unit-11-alpha-olefins-hydr...
The Sulfolactone hydrolysis system consists of a boosting pump, three heat exchangers, and a hydrolyzer. After aging, α- Olefin sulfonate is pumped to the ...Read more
Process for hydrolyzing alpha-olefin sulfonate and system ...
Google Patents
https://patents.google.com › patent
Google Patents
https://patents.google.com › patent
A kind of α olefin sulfonate hydrolysis system is characterized in that: Intake line is communicated with again steam heater and hydrolyzer after connecting the ...Read more
α-Olefin sulfonate
Wikipedia
https://en.wikipedia.org › wiki › Α-Olefin_sulfonate
Wikipedia
https://en.wikipedia.org › wiki › Α-Olefin_sulfonate
Base hydrolysis of the mixture gives alkene sulfonates (derived from simple deprotonation of allylic and homoallylic sulfonic acids) and 3- and 4 ...Read more
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Web results
Alkyl polyglycosides derived from α-olefins via Fisher ...
ScienceDirect.com
https://www.sciencedirect.com › article › abs › pii
ScienceDirect.com
https://www.sciencedirect.com › article › abs › pii
by H Ding2025Cited by 5 — The effective and stable use of α-olefins is a topic of great research interest due to their abundant reserves, and the fact that the hydrolysis ...Read more
Establishing an enzyme cascade for one-pot production of α ...
Springer Nature Link
https://link.springer.com › article
Springer Nature Link
https://link.springer.com › article
by Y Jiang2020Cited by 38 — In this study, a novel enzyme cascade was developed for one-pot production of α-olefins from low-cost triacylglycerols (TAGs) and natural oils ...Read more
Synthesis of α-hydroxy ketones and aldehydes
Organic Chemistry Portal
https://www.organic-chemistry.org › synthesis › hydroxy...
Organic Chemistry Portal
https://www.organic-chemistry.org › synthesis › hydroxy...
Various terminal olefinic compounds are directly converted into the corresponding α-hydroxy ketones in good yields by potassium permanganate oxidation.Read more
Linear α-Olefins from Linear Internal Olefins by a Boron-Based ...
ACS Publications
https://pubs.acs.org › doi
ACS Publications
https://pubs.acs.org › doi
In the cycle boron effectively acts as a catalyst to enable the contrathermodynamic double-bond isomerization to produce an α-olefin from an internal olefin.Read more
Process for hydrolyzing alpha-olefin sulfonate and system ...
Google Patents
https://patents.google.com › patent
Google Patents
https://patents.google.com › patent
The invention relates to a process for hydrolyzing alpha-olefin sulfonate (AOS) and a corresponding hydrolysis system. The invention aims to provide a ...
Oxidation of Long-Chain α-Olefins Using Environmentally ...
PubMed Central (PMC) (.gov)
https://pmc.ncbi.nlm.nih.gov › articles › PMC7602050
PubMed Central (PMC) (.gov)
https://pmc.ncbi.nlm.nih.gov › articles › PMC7602050
by K Peckh2020Cited by 8 — The new method consisted of oxidizing C30+ α-olefins with hydrogen peroxide (2 equiv.) and subsequent oxidation with oxygen.Read more
Scholarly articles for α-olefins hydrolysis | |
Development of a green process for poly-α-olefin … - Yadav - Cited by 101 Olefins, higher - Lappin - Cited by 20 Polymerization of α-olefins and Hydrogenolysis of the … - Tosin - Cited by 22 | |
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